REFRIGERATION THEORY

Heat, Temperature, and BTUs

Heat and temperature are related, but they are not the same thing. A thermometer tells us the thermal condition of a substance, while heat describes energy that is transferred because of a temperature difference.

HVAC/R technicians constantly work with both ideas. We measure temperatures at coils, refrigerant lines, ducts, and air streams, while equipment capacity and heat transfer are commonly expressed in British Thermal Units.

What You Will Learn

By the end of this lesson you should be able to:

1

Distinguish heat from temperature.

Explain why temperature indicates thermal condition while heat describes energy transfer.

2

Explain molecular motion and temperature.

Relate increasing temperature to increasing molecular motion.

3

Identify common temperature scales.

Recognize Fahrenheit, Celsius, Rankine, and Kelvin and understand the purpose of absolute temperature scales.

4

Define the British Thermal Unit.

Explain what one BTU represents and why BTUs are commonly used in HVAC/R.

5

Separate temperature from heat quantity.

Explain why two objects at the same temperature can contain very different amounts of thermal energy.

6

Relate heat flow to refrigeration.

Understand why heat naturally moves from a warmer substance toward a cooler substance.

Related Concepts, Different Meanings

Heat versus temperature infographic comparing thermal energy transfer with temperature and molecular motion.
Figure 2. Temperature describes thermal condition, while heat describes energy transferred because of a temperature difference.
HEAT

Energy in Transfer

Heat is thermal energy transferred from one substance or location to another because a temperature difference exists.

TEMPERATURE

Thermal Condition

Temperature indicates how hot or cold a substance is and is related to the average kinetic energy of its molecules.

A Thermometer Does Not Measure Total Heat Quantity

A thermometer can tell us that two containers of water are both 70°F, but it does not tell us whether one contains a cup of water or hundreds of gallons. The larger quantity can contain much more thermal energy even though the measured temperature is the same.

Temperature Reflects Molecular Activity

Molecules in matter are constantly moving or vibrating. As energy is added and molecular motion increases, temperature generally rises. As energy is removed and molecular motion decreases, temperature generally falls.

LOWER TEMPERATURE

Less Molecular Motion

Molecules have less average kinetic energy and move or vibrate less rapidly.

HIGHER TEMPERATURE

Greater Molecular Motion

Molecules have greater average kinetic energy and move or vibrate more rapidly.

Temperature Is an Intensity Measurement

Temperature indicates the thermal condition of a substance. It does not by itself tell us the total amount of thermal energy associated with all of the matter present.

Different Scales Describe the Same Physical Condition

HVAC/R technicians in the United States most commonly use the Fahrenheit scale, while Celsius is widely used internationally. Rankine and Kelvin are absolute temperature scales used primarily in scientific and engineering calculations.

°F

Fahrenheit

Commonly used in U.S. HVAC/R work for air, refrigerant, equipment, and ambient temperatures.

°C

Celsius

Commonly used in metric systems and HVAC/R work throughout much of the world.

°R

Rankine

An absolute temperature scale that uses Fahrenheit-sized degree increments and begins at absolute zero.

K

Kelvin

An absolute temperature scale that uses Celsius-sized increments and begins at absolute zero.

For this course: Fahrenheit will be the primary temperature scale used in examples. Celsius values may be included where useful. Rankine and Kelvin are introduced so you understand the idea of absolute temperature, but detailed conversion work is not a major focus here.

The Lower Limit of Temperature

Absolute temperature scales begin at absolute zero, the theoretical lower limit of thermal energy associated with molecular motion.

0°R

Approximately -460°F

0 K

Approximately -273°C

Why Absolute Temperature Exists

Some physical relationships involving gases, pressure, and volume require temperature to be measured from an absolute zero reference rather than from an arbitrary scale such as Fahrenheit or Celsius.

Heat Naturally Moves From Warmer to Cooler

When two substances at different temperatures can exchange heat, thermal energy naturally transfers from the warmer substance toward the cooler substance.

WARMER OBJECT
90°F
HEAT FLOW
COOLER OBJECT
70°F

Heat transfer continues as long as a temperature difference exists. If the two substances eventually reach the same temperature, there is no longer a net heat transfer between them.

Mechanical Refrigeration Uses This Natural Rule

An evaporator is maintained colder than the material or air being cooled, so heat naturally transfers into the evaporator. A condenser is maintained hotter than the surrounding cooling medium, so heat naturally transfers away from the condenser.

The British Thermal Unit

One BTU infographic showing one pound of water increasing in temperature by one degree Fahrenheit after receiving one British Thermal Unit of heat.
Figure 3. One British Thermal Unit represents approximately the amount of heat required to raise the temperature of one pound of water by one degree Fahrenheit.

The British Thermal Unit, abbreviated BTU, is a unit used to describe a quantity of thermal energy.

1 BTU
1 pound of water
raised approximately
1°F
BTU Describes Energy, Not Temperature

A BTU does not mean one degree Fahrenheit. It represents a quantity of energy. The temperature change produced by that energy depends on the amount and type of material receiving it.

More Matter Requires More Energy

If two quantities of the same substance undergo the same temperature increase, the larger quantity requires more heat energy.

1 LB OF WATER
68°F → 69°F
≈ 1 BTU
10 LB OF WATER
68°F → 69°F
≈ 10 BTU
100 LB OF WATER
68°F → 69°F
≈ 100 BTU

This simple relationship uses liquid water as the example. Other materials require different amounts of heat for the same weight and temperature change, which leads us to the idea of specific heat in the next lesson.

Energy Quantity and Rate Are Different

BTU

Quantity of Heat

Describes an amount of thermal energy.

BTU/hr

Rate of Heat Transfer

Describes how quickly thermal energy is being transferred over time.

Equipment Capacity Is a Rate

An air conditioner rated at 24,000 BTU/hr is rated for a rate of heat transfer, not a total lifetime quantity of 24,000 BTU.

Where Technicians Use Heat and Temperature

Air Temperatures

Return-air, supply-air, outdoor-air, and indoor-air temperatures help evaluate heat transfer and system operation.

Refrigerant Temperatures

Suction-line, liquid-line, discharge-line, evaporator, and condenser temperatures help determine refrigerant condition.

Equipment Capacity

Heating and cooling equipment is commonly rated in BTU/hr.

Heat Load

Buildings and refrigerated spaces gain or lose heat at measurable rates that equipment must be sized to handle.

Avoid Confusing These Ideas

“Temperature tells me how much heat is present.”

Temperature indicates thermal condition, not total heat quantity. The amount and type of matter also matter.

“One BTU equals one degree.”

A BTU is an energy quantity. One BTU raises approximately one pound of liquid water by one degree Fahrenheit under the standard definition.

“Heat only moves when equipment makes it move.”

Heat naturally transfers from warmer to cooler substances whenever a heat-transfer path exists.

“BTU and BTU/hr mean the same thing.”

BTU is a quantity of energy. BTU/hr is a rate of energy transfer.

Can You Separate Heat From Temperature?

  1. What does temperature tell us about a substance?
  2. What is heat?
  3. Why can two objects at the same temperature contain different amounts of thermal energy?
  4. What generally happens to molecular motion as temperature increases?
  5. Which temperature scale is most commonly used in U.S. HVAC/R work?
  6. What are Rankine and Kelvin used to represent?
  7. What is absolute zero?
  8. In what direction does heat naturally flow?
  9. What is a British Thermal Unit?
  10. Why does ten pounds of water require more heat than one pound of water for the same temperature increase?
  11. What is the difference between BTU and BTU/hr?
  12. Why must an evaporator be colder than the material being cooled?

What You Should Have Learned

1

Heat and temperature are related but describe different physical concepts.

2

Temperature indicates thermal condition and is related to average molecular motion.

3

Heat is thermal energy transferred because a temperature difference exists.

4

Heat naturally moves from a warmer substance toward a cooler substance.

5

Fahrenheit and Celsius are common temperature scales, while Rankine and Kelvin are absolute scales.

6

One BTU represents approximately the heat required to raise one pound of water by one degree Fahrenheit.

7

The amount of heat required for a temperature change depends partly on how much matter is being heated or cooled.

8

BTU describes an energy quantity, while BTU/hr describes a rate of heat transfer.

NEXT LESSON

Sensible Heat, Latent Heat, and Specific Heat

The next lesson examines what happens to added or removed heat. Sometimes temperature changes. At other times the substance changes state while its temperature remains essentially constant.